15 Aug, 2024
· Chemistry

Match each term to its description

Term

  1. Excess reactant
  2. Limiting reactant
  3. Theoretical yield

Definition

  • A) Reactant that can produce more of the product
  • B) Amount of product predicted to be produced by the given reactants
  • C) Reactant that can produce a lesser amount of the product
Short Answer
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Long Explanation

Explanation

Excess reactant

The excess reactant is the reactant that can produce more of the product. This means it is the substance that remains after a chemical reaction has completed.

Limiting reactant

The limiting reactant is the reactant that can produce a lesser amount of the product. It determines the maximum amount of product that can be formed from the given reactants.

Theoretical yield

The theoretical yield is the amount of product predicted to be produced by the given reactants.

Theoretical Yield= \text{Theoretical Yield} = =moles of limiting reactant×molecular weight of productmoles of reactant in reaction = \frac{\text{moles of limiting reactant} \times \text{molecular weight of product}}{\text{moles of reactant in reaction}}

By identifying the limiting reactant, you can calculate the theoretical yield based on stoichiometric relationships in the balanced chemical equation.

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Johnathan Clark

Chemistry Content Writer at Math AI

Johnathan Clark, with a Master's in Chemistry from the University of São Paulo, is a young high school chemistry teacher and part-time contract writer. His engaging classroom experiments translate into compelling written content that makes chemistry exciting and practical.

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Concept

Excess Reactant

Understanding Excess Reactant

In a chemical reaction, the excess reactant is the substance that remains after the reaction has gone to completion. This occurs because it is present in a quantity greater than what is needed to completely react with the limiting reactant.

Key Concepts

  1. Limiting Reactant: The substance that runs out first, thus determining the maximum amount of product that can be formed.

  2. Stoichiometric Coefficients: The proportions of reactants and products in a balanced chemical equation, which need to be understood to identify the excess reactant.

Example Calculation

Consider the reaction between nitrogen gas (N2\text{N}_2) and hydrogen gas (H2\text{H}_2) to form ammonia (NH3\text{NH}_3):

N2+3H22NH3 \text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3

Let's say we have 5 moles of N2\text{N}_2 and 15 moles of H2\text{H}_2.

  1. Determine the mole ratio from the balanced equation:
N2:H2=1:3\text{N}_2 : \text{H}_2 = 1:3
  1. Calculate the moles of H2\text{H}_2 required for the available N2\text{N}_2:
Moles of H2 needed=Moles of N2×3=5×3=15\text{Moles of } \text{H}_2 \text{ needed} = \text{Moles of } \text{N}_2 \times 3 = 5 \times 3 = 15
  1. Compare the available moles of H2\text{H}_2 with the required moles: Since 15 moles of H2\text{H}_2 are exactly what's needed for 5 moles of N2\text{N}_2, neither reactant would be in excess in this case. Let's modify it to illustrate.

  2. If you had 6 moles of N2\text{N}_2:

Moles of H2 needed=6×3=18\text{Moles of } \text{H}_2 \text{ needed} = 6 \times 3 = 18

Since only 15 moles of H2\text{H}_2 are available, it becomes the limiting reactant and N2\text{N}_2 is the excess reactant.

Example Calculation (continued)

  1. The amount of the excess reactant remaining can be calculated:
Used N2=Available H23=153=5 moles\text{Used } \text{N}_2 = \frac{\text{Available } \text{H}_2 \text{}}{3} = \frac{15}{3} = 5 \text{ moles} Excess N2=Initial N2 - Used N2=65=1 mole\text{Excess } \text{N}_2 = \text{Initial } \text{N}_2 \text{ - Used } \text{N}_2 = 6 - 5 = 1 \text{ mole}

Conclusion

Understanding limiting and excess reactants allows for efficient usage of materials and can help predict the quantities of products formed in a reaction. Properly performing these calculations is crucial in both academic and industrial chemical settings.

Concept

Limiting Reactant

Understanding the Limiting Reactant

In a chemical reaction, the limiting reactant is the substance that is completely consumed first and thus determines the amount of product that can be formed. Reactions stop when the limiting reactant is used up, preventing further production of products.

Stoichiometry of the Reaction

To identify the limiting reactant, you need to use the stoichiometric coefficients from the balanced chemical equation. For example, consider the following reaction:

2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O

Steps to Identify the Limiting Reactant

  1. Write the balanced chemical equation for the reaction.
  2. Convert all given reactant quantities (often in grams) to moles using their molar masses.
  3. Use the stoichiometric coefficients from the balanced equation to determine the mole ratio required for the reaction.
  4. Compare the mole ratio of the given reactants with the required mole ratio to identify the reactant that is limiting.

Example Calculation

Suppose we have 5 moles of H2H_2 and 2 moles of O2O_2. To find the limiting reactant:

  1. Balanced Equation: 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O

  2. Mole Ratios from the Balanced Equation:

  • 22 moles of H2H_2 react with 11 mole of O2O_2.
  1. Determine the Theoretical Quantities Needed:
  • For 5 moles of H2H_2: Required moles of O2=5 moles H2×1 mole O22 moles H2=2.5 moles O2\text{Required moles of } O_2 = \frac{5 \text{ moles } H_2 \times 1 \text{ mole } O_2}{2 \text{ moles } H_2} = 2.5 \text{ moles } O_2
  1. Compare Available Moles:
  • We have only 2 moles of O2O_2, but 2.5 moles are required.

Therefore, O2O_2 is the limiting reactant because we do not have enough O2O_2 to completely react with the available H2H_2.

Key Points

  • The limiting reactant runs out first, limiting the amount of product.
  • Excess reactants are those that are left over after the reaction is complete.
  • Identifying the limiting reactant is crucial for calculating the theoretical yield of the reaction.

By understanding and identifying the limiting reactant, chemists can predict the amounts of products formed and optimize the use of reactants in industrial processes.